DMF-exfoliated graphene for electrochemical NADH detection

被引：80

作者：

Keeley, Gareth P. ^{[1
,2
,3
]}

O'Neill, Arlene ^{[2
,4
]}

Holzinger, Michael ^{[1
]}

Cosnier, Serge ^{[1
]}

Coleman, Jonathan N. ^{[2
,4
]}

Duesberg, Georg S. ^{[2
,3
]}

机构：

[1] Univ Grenoble 1, ICMG FR 2607, UMR 5250, Dept Chim Mol,CNRS, F-38041 Grenoble 9, France

[2] Ctr Res Adapt Nanostruct & Nanodevices CRANN, Dublin 2, Ireland

[3] Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland

[4] Trinity Coll Dublin, Sch Phys, Dublin 2, Ireland

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2011年 / 13卷 / 17期

关键词：

CARBON NANOTUBES; PYROLYTIC-GRAPHITE; DIAMOND ELECTRODES; GLASSY-CARBON; BIOSENSORS; FILMS;

D O I：

10.1039/c1cp20060g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrochemical detection of NADH is of considerable interest because it is required as a cofactor in a large number of dehydrogenase-based biosensors. However, the presence of oxygenated functionalities on the electrode often causes fouling due to the adsorption of the oxidised form, NAD(+). Here we report an electroanalytical NADH sensor based on DMF-exfoliated graphene. The latter is shown to have a very low oxygen content, facilitating the exceptionally stable and sensitive detection of this important analyte.

引用

页码：7747 / 7750

页数：4

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