Efficient and practical polymeric catalysts for heterogeneous asymmetric dihydroxylation of olefins

被引：76

作者：

Song, CE ^{[1
]}

Yang, JW ^{[1
]}

Ha, HJ ^{[1
]}

Lee, SG ^{[1
]}

机构：

[1] HANKUK UNIV FOREIGN STUDIES,DEPT CHEM,YONGIN 449791,SOUTH KOREA

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 03期

关键词：

D O I：

10.1016/0957-4166(96)00054-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

High enantioselectivity (>99% ee) and reactivity in heterogeneous catalytic asymmetric dihydroxylation (AD) of olefins have been achieved using new polymeric cinchona alkaloids containing 1,4-bis(9-O-quininyl)phthalazine ((QN)(2)-PHAL), which can be synthesized more economically than their homogeneous analogue, 1,4-bis(9-O-dihydroquininyl)phthalazine ((DHQ)(2)-PHAL). (C) 1996 Elsevier Science Ltd

引用

页码：645 / 648

页数：4

共 17 条

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