2-furyl phosphines as ligands for transition-metal-mediated organic synthesis

被引：227

作者：

Andersen, NG ^{[1
]}

Keay, BA ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 04期

关键词：

D O I：

10.1021/cr000024o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The role of 2-Furyl phosphines as ligands for transition-metal-mediated organic synthesis was discussed. The steric and electronic properties of phosphorus(III) ligands with emphasis on phosphines bearing the 2-furyl group were analyzed. It was found that Stille coupling with tri-2-furylphosphine (TFP) ligand allows for milder reaction conditions and hence the attenuation of unwanted side reactions.

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页码：997 / 1030

页数：34

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