Controlling dimensionality of silver(I) coordination networks with rigid aliphatic amino ligands: from a 2D to a 3D network of unprecedented topology comprising helical channels

被引:24
作者
Seeber, G [1 ]
Pickering, AL [1 ]
Long, DL [1 ]
Cronin, L [1 ]
机构
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
关键词
D O I
10.1039/b305188a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ligand-directed 2D and 3D Ag(I) coordination networks are self-assembled from the rigid, topologically related tri-amino ligands cis-3,5-diaminopiperidine (cis-dapi) and cis, trans-1,3,5- triaminocyclohexane (trans-tach), yielding two networks of differing dimensionality including a 3D network of unprecedented topology comprising helical channels.
引用
收藏
页码:2002 / 2003
页数:2
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