Optoelectronic devices based on evaporated pentacene films

被引:29
作者
Voz, C [1 ]
Puigdollers, J [1 ]
Martín, I [1 ]
Muñoz, D [1 ]
Orpella, A [1 ]
Vetter, M [1 ]
Alcubilla, R [1 ]
机构
[1] Univ Politecn Catalunya, Dept Elect Engn, ES-08034 Barcelona, Spain
关键词
pentacene; schottky diode; excitons;
D O I
10.1016/j.solmat.2004.07.039
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Aluminium/pentacene Schottky diodes have been fabricated on glass substrates. An ohmic, transparent front contact was prepared by sputtering a highly conductive indium-tin-oxide layer. The pentacene layer was evaporated in high vacuum of a pure (98%) commercially available source. All the samples were grown at room temperature and moderate deposition rates (< 10 angstrom/s). Optical measurements evidence absorption peaks at energy positions 1.86, 1.97, 2.13, 2.3 and 2.5 eV, corresponding to singlet states of the lowest unoccupied molecular orbital of pentacene. The current-voltage characteristics show good rectifying behaviours. Finally, a clear antibatic response is observed in the external quantum efficiency of the photodiodes when illuminated through the indium-tin-oxide contact. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:567 / 573
页数:7
相关论文
共 12 条
[1]   THERMOOPTICAL SPECTROSCOPY - DETECTION BY THE MIRAGE EFFECT [J].
BOCCARA, AC ;
FOURNIER, D ;
BADOZ, J .
APPLIED PHYSICS LETTERS, 1980, 36 (02) :130-132
[2]   Morphology identification of the thin film phases of vacuum evaporated pentacene on SIO2 substrates [J].
Bouchoms, IPM ;
Schoonveld, WA ;
Vrijmoeth, J ;
Klapwijk, TM .
SYNTHETIC METALS, 1999, 104 (03) :175-178
[3]   Flexible active-matrix displays and shift registers based on solution-processed organic transistors [J].
Gelinck, GH ;
Huitema, HEA ;
Van Veenendaal, E ;
Cantatore, E ;
Schrijnemakers, L ;
Van der Putten, JBPH ;
Geuns, TCT ;
Beenhakkers, M ;
Giesbers, JB ;
Huisman, BH ;
Meijer, EJ ;
Benito, EM ;
Touwslager, FJ ;
Marsman, AW ;
Van Rens, BJE ;
De Leeuw, DM .
NATURE MATERIALS, 2004, 3 (02) :106-110
[4]   MEROCYANINE ORGANIC SOLAR-CELLS [J].
GHOSH, AK ;
FENG, T .
JOURNAL OF APPLIED PHYSICS, 1978, 49 (12) :5982-5989
[5]   Analysis of the photocurrent action spectra of MEH-PPV polymer photodiodes [J].
Harrison, MG ;
Gruner, J ;
Spencer, GCW .
PHYSICAL REVIEW B, 1997, 55 (12) :7831-7849
[6]   Conjugated organic molecules on metal versus polymer electrodes: Demonstration of a key energy level alignment mechanism [J].
Koch, N ;
Kahn, A ;
Ghijsen, J ;
Pireaux, JJ ;
Schwartz, J ;
Johnson, RL ;
Elschner, A .
APPLIED PHYSICS LETTERS, 2003, 82 (01) :70-72
[7]   Correlation between photoelectric and optical absorption spectra of thermally evaporated pentacene films [J].
Lee, J ;
Kim, SS ;
Kim, K ;
Kim, JH ;
Im, S .
APPLIED PHYSICS LETTERS, 2004, 84 (10) :1701-1703
[8]   Optical and luminescence characteristics of thermally evaporated pentacene films on Si [J].
Park, SP ;
Kim, SS ;
Kim, JH ;
Whang, CN ;
Im, S .
APPLIED PHYSICS LETTERS, 2002, 80 (16) :2872-2874
[9]  
Pope M., 1999, ELECT PROCESSES ORGA
[10]   Pentacene thin-films obtained by thermal evaporation in high vacuum [J].
Puigdollers, J ;
Voz, C ;
Orpella, A ;
Martin, I ;
Vetter, M ;
Alcubilla, R .
THIN SOLID FILMS, 2003, 427 (1-2) :367-370