Cyclic phosphorochloridites, phosphorochloridates, and phosphorochloridothioates based on calix[4]resorcinolarenes

被引:6
作者
Nikolaeva, IL [1 ]
Burilov, AR
Kharitonov, DI
Pudovik, MA
Habicher, WD
Konovalov, AI
机构
[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Sci Ctr, Kazan, Tatarstan, Russia
[2] Dresden Univ Technol, Inst Organ Chem, D-8027 Dresden, Germany
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1023/A:1012361102571
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phosphorylation of calix[4]resorcinolarenes with PCl3 yields cyclic phosphorochloridites. Cavitands containing cyclic phosphorochloridite fragments in the upper rim are readily oxidized with SO2Cl2 to the corresponding phosphorochloridates and take up four equivalents of sulfur on heating to form cyclic phosphorochloridothioates.
引用
收藏
页码:379 / 382
页数:4
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