Tetraphosphonate-calix[4]resorcinarene. A powerful host for alkali metal and ammonium cations encapsulation.

被引：47

作者：

Delangle, P ^{[1
]}

Dutasta, JP ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER LYON,STEREOCHIM & INTERACT MOLEC,CNRS,F-69364 LYON 07,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 51期

关键词：

D O I：

10.1016/0040-4039(95)02031-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tetraphosphonate calix[4]resorcinarene 1 has been isolated in its iiii conformation with the four P=O groups pointing inwards. Complexation studies proved 1 to be an efficient extractant and a powerful ligand for alkali metals and ammonium cations. It is assumed that the phosphorylated crown delineating the upper rim of the cavity and the aromatic cavity act cooperatively by means of ion dipole and specific x-interactions for encapsulation of size adapted cationic species.

引用

页码：9325 / 9328

页数：4

共 52 条

[1] MACROPOLYCYCLIC POLYETHERS (CAGES) AND RELATED-COMPOUNDS [J].

AN, HY ;

BRADSHAW, JS ;

IZATT, RM .

CHEMICAL REVIEWS, 1992, 92 (04) :543-572

[2] MOLECULAR RECOGNITION .5. MOLECULAR RECOGNITION OF SUGARS VIA HYDROGEN-BONDING INTERACTION WITH A SYNTHETIC POLYHYDROXY MACROCYCLE [J].

AOYAMA, Y ;

TANAKA, Y ;

SUGAHARA, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) :5397-5404

[3] REDOX-ACTIVE CAVITAND HOST MOLECULES CONTAINING MULTIPLE FERROCENYL REDOX CENTERS - SYNTHESES, CRYSTAL-STRUCTURE, MOLECULAR MECHANICS CALCULATIONS, AND ELECTROCHEMICAL PROPERTIES [J].

BEER, PD ;

TITE, EL ;

DREW, MGB ;

IBBOTSON, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08) :2543-2550

[4] NEW HYDROPHOBIC HOST MOLECULES CONTAINING MULTIPLE REDOX-ACTIVE CENTERS [J].

BEER, PD ;

TITE, EL .

TETRAHEDRON LETTERS, 1988, 29 (19) :2349-2352

[5] REDOX-ACTIVE CAVITAND HOST MOLECULES CONTAINING MULTIPLE REDOX CENTERS, SYNTHESES AND X-RAY CRYSTAL-STRUCTURE OF A DICHLOROMETHANE INCLUSION COMPLEX [J].

BEER, PD ;

DREW, MGB ;

IBBOTSON, A ;

TITE, EL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) :1498-1500

[6]

Cram D. J., 1994, CONTAINER MOL THEIR, V4

[7] THE DESIGN OF MOLECULAR HOSTS, GUESTS, AND THEIR COMPLEXES (NOBEL LECTURE) [J].

CRAM, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08) :1009-1020

[8] COMPLEMENTARY SOLUTES ENTER NONPOLAR PREORGANIZED CAVITIES IN LIPOPHILIC NONCOMPLEMENTARY MEDIA [J].

CRAM, DJ ;

STEWART, KD ;

GOLDBERG, I ;

TRUEBLOOD, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (08) :2574-2575

[9] HOST-GUEST COMPLEXATION .62. SOLVOPHOBIC AND ENTROPIC DRIVING FORCES FOR FORMING VELCRAPLEXES, WHICH ARE 4-FOLD, LOCK-KEY DIMERS IN ORGANIC MEDIA [J].

CRAM, DJ ;

CHOI, HJ ;

BRYANT, JA ;

KNOBLER, CB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (20) :7748-7765

[10] MOLECULAR CONTAINER COMPOUNDS [J].

CRAM, DJ .

NATURE, 1992, 356 (6364) :29-36

← 1 2 3 4 5 6 →