Two luminescent 2D layered copper(I)-olefin coordination polymers with high thermal stability

被引：54

作者：

Zhang, J

Xiong, RG ^{[1
]}

Chen, XT

Che, CM

Xue, ZL

You, XZ

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 19期

关键词：

D O I：

10.1021/om001033q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal reactions of 3-pyridylacrylic acid (3-HPYA) and 2-pyridylacrylic acid (2-HPYA) with Cu(CH3CN)(4)BF4 yield two novel highly stable copper(I)-olefin coordination polymers, [(3-PYA)Cu(I)]n (1) and {[(2-PYA)Cu(I)]. (H2O)}n (2), respectively. Both polymers display 2D layered structures and yellow fluorescent emission in the solid state.

引用

页码：4118 / 4121

页数：4

共 36 条

[1]

[Anonymous], COMPREHENSIVE ORGANO

[2]

Cavallo L, 2000, CHEM-EUR J, V6, P1127, DOI 10.1002/(SICI)1521-3765(20000403)6:7<1127::AID-CHEM1127>3.3.CO

[3]

2-X

[4] Cooperative substituent effects on the excited states of copper phenanthrolines [J].