Limitations to n-type doping in diamond: The phosphorus-vacancy complex

被引:68
作者
Jones, R [1 ]
Lowther, JE [1 ]
Goss, J [1 ]
机构
[1] UNIV EXETER,DEPT PHYS,EXETER EX4 4QL,DEVON,ENGLAND
关键词
D O I
10.1063/1.117715
中图分类号
O59 [应用物理学];
学科分类号
摘要
In spite of large concentrations of phosphorus being incorporated into. diamond, the material often remains insulating. It is argued that this occurs through the formation of phosphorus-vacancy complexes which are deep accepters and compensate any donor. The complex is analyzed using a first-principles cluster method. In the ionized state, the defect is diamagnetic and cannot give rise to any internal optical transitions although broad band donor-acceptor transitions are expected-and observed-in material codoped with nitrogen. (C) 1996 American Institute of Physics.
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页码:2489 / 2491
页数:3
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