Supramolecular Self-Assembly Induced Graphene Oxide Based Hydrogels and Organogels

被引:88
作者
Cheng, Qian-Yi [1 ,2 ]
Zhou, Ding [1 ]
Gao, Yun [1 ]
Chen, Qi [1 ]
Zhang, Zhong [1 ]
Han, Bao-Hang [1 ]
机构
[1] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
基金
美国国家科学基金会;
关键词
GRAPHITE OXIDE; DISPERSIONS;
D O I
10.1021/la204558f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate the construction of three-dimensional graphene oxide based gel networks through the self-assembly of a series of amphiphilic molecules, which possess a polar carbohydrate headgroup attached to a nonpolar pyrene group. The gelation process can occur in both aqueous and organic solutions and be influenced by the gelators' molecular structure. The driving forces for the gelation process were determined as pi-pi stacking and hydrogen bonding interaction by using fluorescence and infrared spectroscopies. Rheometry was used to investigate the mechanical properties of the hydrogels and the organogels. The hydrogel was investigated to be applied to remove dye from aqueous solution.
引用
收藏
页码:3005 / 3010
页数:6
相关论文
共 33 条
[1]   Graphene Oxide-Based Supramolecular Hydrogels for Making Nanohybrid Systems with Au Nanoparticles [J].
Adhikari, Bimalendu ;
Biswas, Abbijit ;
Banerjee, Arindam .
LANGMUIR, 2012, 28 (02) :1460-1469
[2]   Isostable DNA [J].
Ahlborn, Carolin ;
Siegmund, Karsten ;
Richert, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) :15218-15232
[3]   A pH-sensitive graphene oxide composite hydrogel [J].
Bai, Hua ;
Li, Chun ;
Wang, Xiaolin ;
Shi, Gaoquan .
CHEMICAL COMMUNICATIONS, 2010, 46 (14) :2376-2378
[4]   An insulin-sensing sugar-based fluorescent hydrogel [J].
Bhuniya, S ;
Kim, BH .
CHEMICAL COMMUNICATIONS, 2006, (17) :1842-1844
[5]   Fluorescent Conjugated Polyfluorene with Pendant Lactopyranosyl Ligands for Studies of Ca2+-Mediated Carbohydrate-Carbohydrate Interaction [J].
Chen, Qi ;
Cui, Yi ;
Zhang, Tian-Long ;
Cao, Jie ;
Han, Bao-Hang .
BIOMACROMOLECULES, 2010, 11 (01) :13-19
[6]   Triphenylamine-based fluorescent conjugated glycopolymers: Synthesis, characterization and interactions with lectins [J].
Chen, Qi ;
Xu, Yonghua ;
Du, Yuguo ;
Han, Bao-Hang .
POLYMER, 2009, 50 (13) :2830-2835
[7]   Graphene Oxide-MnO2 Nanocomposites for Supercapacitors [J].
Chen, Sheng ;
Zhu, Junwu ;
Wu, Xiaodong ;
Han, Qiaofeng ;
Wang, Xin .
ACS NANO, 2010, 4 (05) :2822-2830
[8]   Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials [J].
Compton, Owen C. ;
Nguyen, SonBinh T. .
SMALL, 2010, 6 (06) :711-723
[9]   An organogel system can control the stereochemical course of anthracene photodimerization [J].
Dawn, Arnab ;
Fujita, Norifumi ;
Haraguchi, Shuichi ;
Sada, Kazuki ;
Shinkai, Seiji .
CHEMICAL COMMUNICATIONS, 2009, (16) :2100-2102
[10]   Thin-film particles of graphite oxide 1: High-yield synthesis and flexibility of the particles [J].
Hirata, M ;
Gotou, T ;
Horiuchi, S ;
Fujiwara, M ;
Ohba, M .
CARBON, 2004, 42 (14) :2929-2937