An organogel system can control the stereochemical course of anthracene photodimerization

被引：96

作者：

Dawn, Arnab ^{[1
]}

Fujita, Norifumi ^{[1
]}

Haraguchi, Shuichi ^{[1
]}

Sada, Kazuki ^{[1
]}

Shinkai, Seiji ^{[1
]}

机构：

[1] Kyushu Univ, Dept Chem & Biochem, Grad Sch Engn, Fukuoka 8190395, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 16期

关键词：

GEL PHASE-TRANSITION; ENANTIODIFFERENTIATING PHOTOCYCLODIMERIZATION; STEREOSELECTIVE PHOTOCYCLODIMERIZATION; 2-ANTHRACENECARBOXYLIC ACID; ASYMMETRIC PHOTOCHEMISTRY; SUPRAMOLECULAR CATALYSIS; GAMMA-CYCLODEXTRIN; LIGHT; CHIRALITY; PRESSURE;

D O I：

10.1039/b820565e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel photoresponsive organogel with a binary gelator containing 2-anthracenecarboxylic acid shows a high degree of stereochemical control, resulting in head-to-head photocyclodimers exclusively together with significant enantiomeric excess induced by the chiral counterpart of the gelator.

引用

收藏

页码：2100 / 2102

页数：3

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