Template-directed synthesis of donor/acceptor [2]catenanes and [2]rotaxanes

被引：152

作者：

Griffiths, Kirsten E. ^{[1
,2
]}

Stoddart, J. Fraser ^{[1
,2
]}

机构：

[1] Univ Calif Los Angeles, California NanoSyst Inst, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

PURE AND APPLIED CHEMISTRY | 2008年 / 80卷 / 03期

关键词：

2]rotaxanes; 2]catenanes; template-directed synthesis; pseudorotaxanes; donor/acceptor recognition; mechanically interlocked molecules; mechanical bonds; molecular machines; molecular motors; molecular electronics;

D O I：

10.1351/pac200880030485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of mechanically interlocked molecular compounds has advanced by leaps and bounds since the early days of statistical methods and covalent-directing strategies. Template-directed synthesis has emerged as the method of choice for the construction of increasingly complex and functional [2]catenanes and [2]rotaxanes. In particular, mechanically interlocked molecules employing pi-donating and pi-accepting recognition units have been produced with remarkable efficiencies and show great promise in technologies as diverse as molecular electronics and drug delivery.

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收藏

页码：485 / 506

页数：22

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