Low-temperature synthesis of nanosized bismuth ferrite by soft chemical route

被引:295
作者
Ghosh, S [1 ]
Dasgupta, S [1 ]
Sen, A [1 ]
Maiti, HS [1 ]
机构
[1] Cent Glass & Ceram Res Inst, Kolkata 700032, W Bengal, India
关键词
D O I
10.1111/j.1551-2916.2005.00306.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The present research describes a simple low-temperature synthesis route of preparing bismuth ferrite nanopowders through soft chemical route using nitrates of Bismuth and Iron. Tartaric acid is used as a template material and nitric acid as an oxidizing agent. The synthesized powders are characterized by X-ray diffractometry, thermogravimetry and differential thermal analysis, infrared spectroscopy, and scanning electron microscopy. The particle size of the powder lies between 3 and 16 nm. In the process, phase pure bismuth ferrite can be obtained at a temperature as low as 400 degrees C, in contrast to 550 degrees C for coprecipitation route. On the other hand, we find that, like solid state reaction route, Pechini's autocombustion method of synthesis generates a lot of impurity phases along with bismuth ferrite.
引用
收藏
页码:1349 / 1352
页数:4
相关论文
共 12 条
  • [1] PREPARATION OF SINGLE-PHASE POLYCRYSTALLINE BIFEO3
    ACHENBACH, GD
    JAMES, WJ
    GERSON, R
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1967, 50 (08) : 437 - +
  • [2] Coordination complexes of bismuth(III) involving organic ligands with pnictogen or chalcogen donors
    Briand, GG
    Burford, N
    [J]. ADVANCES IN INORGANIC CHEMISTRY, VOL 50: MAIN GROUP CHEMISTRY, 2000, 50 : 285 - 357
  • [3] PRECISION DETERMINATION OF LATTICE PARAMETERS AND COEFFICIENTS OF THERMAL EXPANSION OF BIFEO3
    BUCCI, JD
    ROBERTSO.BK
    JAMES, WJ
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1972, 5 (JUN1) : 187 - &
  • [4] METAL-COMPLEXES IN BIOLOGY AND MEDICINE .5. NEW BISMUTH HYDROXYCARBOXYLATE COMPLEXES - SYNTHESIS AND STRUCTURE OF BISMUTH(III) MALATE MONOHYDRATE AND BISMUTH(III) TARTRATE TRIHYDRATE
    HERRMANN, WA
    HERDTWECK, E
    SCHERER, W
    KIPROF, P
    PAJDLA, L
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (01): : 51 - 56
  • [5] STRUCTURE OF A FERROELECTRIC AND FERROELASTIC MONODOMAIN CRYSTAL OF THE PEROVSKITE BIFEO3
    KUBEL, F
    SCHMID, H
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1990, 46 : 698 - 702
  • [6] CRYSTAL CHEMISTRY OF RARE EARTH ORTHOFERRITES
    MAREZIO, M
    REMEIKA, JP
    DERNIER, PD
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 (DEC15): : 2008 - &
  • [7] OPTICALLY ACTIVE CRYSTAL VIBRATIONS OF ALKALI-METAL NITRATES
    NAKAGAWA, I
    WALTER, JL
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (04) : 1389 - +
  • [8] BiFeO3 thin films:: Novel effects
    Palkar, VR
    Pinto, R
    [J]. PRAMANA-JOURNAL OF PHYSICS, 2002, 58 (5-6): : 1003 - 1008
  • [9] Pechini M.P, 1967, US Pat. Off., Patent No. [3330697, 3,330,697]
  • [10] Size effect study in magnetoelectric BiFeO3 system
    Shetty, S
    Palkar, VR
    Pinto, R
    [J]. PRAMANA-JOURNAL OF PHYSICS, 2002, 58 (5-6): : 1027 - 1030