METAL-COMPLEXES IN BIOLOGY AND MEDICINE .5. NEW BISMUTH HYDROXYCARBOXYLATE COMPLEXES - SYNTHESIS AND STRUCTURE OF BISMUTH(III) MALATE MONOHYDRATE AND BISMUTH(III) TARTRATE TRIHYDRATE

被引:29
作者
HERRMANN, WA
HERDTWECK, E
SCHERER, W
KIPROF, P
PAJDLA, L
机构
[1] Anorganisch-Chemisches Institut, Technischen Universität München, Garching, W-8046
来源
CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 01期
关键词
BISMUTH; MALATE; TARTRATE;
D O I
10.1002/cber.19931260109
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of Bi(NO3)3 . 5 H2O with L-(-)-malic acid results in the formation of bismuth(III) malate monohydrate Bi[O2CCH2CH(O)CO2] . H2O (1) containing the tridentate ligand [L-(-)-malate]3- with all donating functions deprotonated. By way of contrast, reaction of Bi(NO3)3 . 5 H2O with L-(+)-tartraic acid gives bismuth(III) tartrate trihydrate (2), in which two different tartrate ligands, [L-(+)-tartrate]1- and [L-(+)-tartrate]2- are present. The solid-state structures have been determined by single-crystal X-ray methods and confirmed by powder diffraction measurements. The structure analyses exhibit a three-dimensional network in the crystalline state resulting from bridging and chelating properties of the polydentate hydroxycarboxylate ligands. Bismuth shows high coordination numbers.
引用
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页码:51 / 56
页数:6
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