Metal-free catalytic hydrogenation

被引：516

作者：

Chase, Preston A. ^{[1
]}

Welch, Gregory C. ^{[1
]}

Jurca, Titel ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 42期

关键词：

boron; dihydrogen; homogeneous catalysis; hydrogenation; phosphorus;

D O I：

10.1002/anie.200702908

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Phosphonium borates of the form R 2PH-(C6F4)BH(C6F5) 2 are shown to be metalfree hydrogenation catalysts (see scheme) that effect reduction of sterically hindered imines and aziridines, as well as B(C6F5)3-protected unhindered imines and nitriles, at relatively low H2 pressures and temperatures. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8050 / 8053

页数：4

共 29 条

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