Reduction of nitrogen monoxide with propene over Au/Al2O3 mixed mechanically with Mn2O3

被引：93

作者：

Ueda, A ^{[1
]}

Haruta, M ^{[1
]}

机构：

[1] Osaka Natl Res Inst, AIST, Ikeda, Osaka 5638577, Japan

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 1998年 / 18卷 / 1-2期

关键词：

NO reduction; gold catalysts; manganese oxide; propene; mechanical mixing;

D O I：

10.1016/S0926-3373(98)00026-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reduction of NO with propene in the presence of excess oxygen and moisture over gold supported on Al2O3 is appreciably enhanced by the addition of Mn2O3 through mechanical mixing. The conversion of NO to Nz is markedly improved at temperatures below 573 K, above which it reaches 98% without appreciable decrease with an increase in temperature. The conversion of NO increases with an increase in O-2 concentration up to 5 vol%, and thereafter it levels off. The role of Mn2O3 is proven to enhance NO2 formation by the reaction of NO with oxygen. (C) 1998 Elsevier Science B.V. All rights reserved.

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页码：115 / 121

页数：7

相关论文

共 37 条

[11] HIGH CATALYTIC ACTIVITY OF PLATINUM-ZSM-5 ZEOLITE BELOW 500-K IN WATER-VAPOR FOR REDUCTION OF NITROGEN MONOXIDE [J].

HIRABAYASHI, H ;

YAHIRO, H ;

MIZUNO, N ;

IWAMOTO, M .

CHEMISTRY LETTERS, 1992, (11) :2235-2236

[12]

Hirao Y., 1996, J CHEM SOC CHEM COMM, P597

[13] Silica-supported cobalt catalysts for the selective reduction of nitrogen monoxide with propene [J].

Inaba, M ;

Kintaichi, Y ;

Haneda, M ;

Hamada, H .

CATALYSIS LETTERS, 1996, 39 (3-4) :269-274

[14] REMOVAL OF NITRIC-OXIDE ON METALLOSILICATE CATALYSTS [J].

INUI, T ;

IWAMOTO, S ;

KOJO, S ;

SHIMIZU, S ;

HIRABAYASHI, T .

CATALYSIS TODAY, 1994, 22 (01) :41-57

[15]

IWAMOTO M, 1993, J AUTO ENG, V207, P23

[16] Promotive effect of additives to In/H-ZSM-5 catalyst for selective reduction of nitric oxide with methane in the presence of water vapor [J].

Kikuchi, E ;

Ogura, M ;

Aratani, N ;

Sugiura, Y ;

Hiromoto, S ;

Yogo, K .

CATALYSIS TODAY, 1996, 27 (1-2) :35-40

[17] SELECTIVE CATALYTIC REDUCTION OF NITROGEN-OXIDE BY HYDROCARBONS OVER MORDENITE-TYPE ZEOLITE CATALYSTS [J].

KIM, MH ;

NAM, IS ;

KIM, YG .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1995, 6 (04) :297-310

[18] Water tolerance of mordenite-type zeolite catalysts for selective reduction of nitric oxide by hydrocarbons [J].

Kim, MH ;

Nam, IS ;

Kim, YG .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 12 (2-3) :125-145

[19] Rearrangement of cationic sites in CuH-ZSM-5 and reactivity loss upon high-temperature calcination and steam aging [J].

Kucherov, AV ;

Hubbard, CP ;

Shelef, M .

JOURNAL OF CATALYSIS, 1995, 157 (02) :603-610

[20] EFFECT OF WATER-VAPOR ON THE SELECTIVE REDUCTION OF NO BY METHANE OVER COBALT-EXCHANGED ZSM-5 [J].

LI, YJ ;

BATTAVIO, PJ ;

ARMOR, JN .

JOURNAL OF CATALYSIS, 1993, 142 (02) :561-571

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