Novel fluoroalkene-methyl acrylate copolymers by atom transfer radical polymerization

被引：34

作者：

Borkar, S ^{[1
]}

Sen, A ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

MACROMOLECULES | 2005年 / 38卷 / 07期

关键词：

D O I：

10.1021/ma047532a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The first controlled atom transfer radical polymerization (ATRP) of methyl acrylate (MA) with fluoralkenes was demonstrated. The copolymerization rate and the extent of alkene incorporation are higher that those observed with simple 1-alkenes. The unique block terpolymer, poly[(MA-co-ethene)-b-(MA-co-nonafluorohexene)], was also synthesized by sequential addition of ethene and nonafluoro-1-hexene to an acrylate copolymerization system. The perfluorination of the pendant alkyl group increases monomer reactivity, as with styrene. The polymerization reaction kinetics of MA with three fluoroalkene comonomers F-hexene, F-octene, and F-decene were performed in anisole solution.

引用

页码：3029 / 3032

页数：4

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