Structure and magnetism of the first cyano-bridged hetero-one-dimensional GdIII-CrIII complexes

被引:97
作者
Figuerola, A
Diaz, C
El Fallah, MS
Ribas, J
Maestro, M
Mahía, JE
机构
[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[2] Univ A Coruna, Fac Ciencias, Serv Xerais Apoio Invest, E-15071 La Coruna, Spain
关键词
D O I
10.1039/b102739p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A reaction between Gd(NO3)(3). 6H(2)O, K-3[Cr(CN)(6)] and dmf or bpy has allowed the synthesis of two new ferrimagnetic Gd-III-Cr-III chains which are the first low-dimensional 4f-Cr-III systems; magnetic susceptibilty data indicate antiferromagnetic coupling between Gd-III and Cr-III.
引用
收藏
页码:1204 / 1205
页数:2
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