Heck reactions with various types of palladium complex catalysts: application of multiphase catalysis and supercritical carbon dioxide

被引:57
作者
Bhanage, BM [1 ]
Fujita, S [1 ]
Arai, M [1 ]
机构
[1] Hokkaido Univ, Grad Sch Engn, Div Mat Sci & Engn, Sapporo, Hokkaido 0608628, Japan
关键词
Heck reaction; biphasic catalysis; supported liquid phase catalyst; supercritical carbon dioxide; SOLUBLE METAL-COMPLEXES; METHYL ACRYLATE; ETHYLENE-GLYCOL; COUPLING REACTIONS; ARYL CHLORIDES; LIQUID; WATER; IODOBENZENE; LIGANDS; TRIPHENYLPHOSPHINE;
D O I
10.1016/j.jorganchem.2003.09.006
中图分类号
O61 [无机化学];
学科分类号
070301 [无机化学];
摘要
The application of multiphase catalytic systems for palladium catalyzed Heck reactions brings several benefits such as easy catalyst-product separation and catalyst recycling. The effective multiphase Heck systems can be prepared by using different types of catalyst phases, including biphasic catalysis and supported liquid phase catalysts, and a new generation solvent of supercritical carbon dioxide. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:211 / 218
页数:8
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