Chiral monophosphites derived from carbohydrate: Conformational effect in catalytic asymmetric hydrogenation

被引：59

作者：

Huang, HM ^{[1
]}

Zheng, Z ^{[1
]}

Luo, HL ^{[1
]}

Bai, CM ^{[1
]}

Hu, XQ ^{[1
]}

Chen, HL ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 22期

关键词：

D O I：

10.1021/ol035551j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The carbohydrate-derived chiral monophosphites with additional groups have been synthesized and used for asymmetric hydrogenation of dimethyl itaconate and enamides. Up to 99.6% ee and 98.5% ee have been obtained, respectively.

引用

页码：4137 / 4139

页数：3

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