First aminosilyl bridging ligand in a bimetallic complex: Structure of [(OC)(3){(Me(2)N)(2)(MeO)P}Fe{mu-Si(OMe)(2)(NMe(2))}Cu(PPh(3))]

被引：13

作者：

Braunstein, P ^{[1
]}

Stern, C ^{[1
]}

Strohmann, C ^{[1
]}

Tong, N ^{[1
]}

机构：

[1] UNIV SAARLAND,D-66041 SAARBRUCKEN,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 19期

关键词：

D O I：

10.1039/cc9960002237

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of a bridging aminosilyl ligand between two transition metals is reported and the crystal structure of the bimetallic complex [(OC)(3){(Me(2)N)(2)(MeO)P}Fe{mu-Si(OMe)(2)(NMe(2))}Cu(PPh(3))] establishes the presence of an unprecedented four-membered cycle; selective metal-promoted OMe/NMe(2) substituent exchange between P and Si occurs-during the synthesis of the iron-silylene precursor.

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页码：2237 / 2238

页数：2

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