REACTIVITY OF HETEROBIMETALLIC ALKOXYSILYL AND SILOXYL COMPLEXES IN THE DEHYDROGENATIVE COUPLING OF STANNANES

被引：17

作者：

BRAUNSTEIN, P

MORISE, X

BLIN, J

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 14期

关键词：

D O I：

10.1039/c39950001455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterobimetallic iron-palladium alkoxysilyl- and siloxyl-complexes catalyse the dehydrogenative tin-tin coupling reaction; high turnover numbers are obtained, whereas modifications of the silicon-containing ligand strongly influence the efficiency of the catalyst.

引用

页码：1455 / 1456

页数：2

共 13 条

[1] SYNTHESIS AND STRUCTURE OF BIMETALLIC ALLYL, ALKOXYSILYL COMPLEXES [FE(SI(OME)3)(CO)3(MU-DPPM)M(ETA-3-2-RC3H4)] (M = PD, PT, R = H, ME) AND OF [FE(MU-SI(OME)2(OME))(CO)3(MU-DPPM)PD(SNPH3)], A SN-PD-FE-SI CHAIN COMPLEX WITH A MU-2-ETA-2-SIO BRIDGE [J].