Mesoporous polyhedral cages and shells formed by textured self-assembly of ZnO nanocrystals

被引：401

作者：

Gao, PX ^{[1
]}

Wang, ZL ^{[1
]}

机构：

[1] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 37期

关键词：

D O I：

10.1021/ja035569p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a new structure, mesoporous structured polyhedral drum and spherical cages and shells formed by textured self-assembly of ZnO nanocrystals, which are made by a novel self-assembly process during epitaxial surface oxidation. The cages/shells exhibit unique geometrical shapes, and their walls are composed of mesoporous and textured ZnO nanocrystals. The structures of the cages and shells are studied, and a growth mechanism is proposed to be a process following solidification of the Zn liquid droplets, surface oxidation, and sublimation.

引用

页码：11299 / 11305

页数：7

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