Probing every layer in dendrons

被引:28
作者
Sivanandan, K
Aathimanikandan, SV
Arges, CG
Bardeen, CJ
Thayumanavan, S [1 ]
机构
[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
[2] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
关键词
D O I
10.1021/ja043356+
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dendrons with a fluorescent probe in a specific location have been synthesized and characterized. Accessibility of guest molecules to each of these layers was then analyzed using an intermolecular photoinduced electron-transfer process. Comparisons of the accessibility among each layer of the dendron and among the generations are provided. Copyright © 2005 American Chemical Society.
引用
收藏
页码:2020 / 2021
页数:2
相关论文
共 24 条
  • [1] ANDRONOV A, 2000, J CHEM SOC CHEM COMM, P1701
  • [2] Dendritic catalysts and dendrimers in catalysis
    Astruc, D
    Chardac, F
    [J]. CHEMICAL REVIEWS, 2001, 101 (09) : 2991 - 3023
  • [3] Bo ZS, 1999, ANGEW CHEM INT EDIT, V38, P2370, DOI 10.1002/(SICI)1521-3773(19990816)38:16<2370::AID-ANIE2370>3.3.CO
  • [4] 2-K
  • [5] About dendrimers: Structure, physical properties, and applications
    Bosman, AW
    Janssen, HM
    Meijer, EW
    [J]. CHEMICAL REVIEWS, 1999, 99 (07) : 1665 - 1688
  • [6] Electrochemistry of encapsulated redox centers
    Cardona, CM
    Mendoza, S
    Kaifer, AE
    [J]. CHEMICAL SOCIETY REVIEWS, 2000, 29 (01) : 37 - 42
  • [7] FRECHET JM, 2002, DENDRIMERS DENDRITIC
  • [8] Stimuli-responsive supramolecular assemblies of linear-dendritic copolymers
    Gillies, ER
    Jonsson, TB
    Fréchet, JMJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (38) : 11936 - 11943
  • [9] Structure-property relationships in dendritic encapsulation
    Gorman, CB
    Smith, JC
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (01) : 60 - 71
  • [10] Synthesis and surface functionalization of aliphatic polyether dendrons
    Grayson, SM
    Fréchet, JMJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (42) : 10335 - 10344