Ultrasonic effects on electroorganic processes - XI. Emulsion and suspension electrolyses under ultrasonic irradiation

被引：14

作者：

Atobe, M ^{[1
]}

Chen, PC ^{[1
]}

Nonaka, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

DENKI KAGAKU | 1998年 / 66卷 / 05期

关键词：

ultrasonic irradiation; electrolysis; emulsion; suspension;

D O I：

10.5796/kogyobutsurikagaku.66.556

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Ultrasonic effects on emulsion and suspension electrolyses were examined using model reactions for direct and/or indirect, and cathodic reduction and/or anodic oxidation from a practical aspect of electroorganic synthesis. In most cases, the current efficiencies were increased by ultrasonic irradiation, though those were complicatedly influenced by rate of mechanical stirring for emulsifying and suspending the electrolytic solutions regardless of the irradiation. A mechanism for occurrence of the ultrasonic effects was preliminarily discussed on the basis of promotion of mass transport by ultrasounds.

引用

收藏

页码：556 / 559

页数：4

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