Synthesis, resolution and application of 2,2′-bis(di-2-furylphosphino)-1,1′-binaphthalene

被引：37

作者：

Andersen, NG

McDonald, R

Keay, BA ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0957-4166(01)00035-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A six step synthesis and resolution of (+/-)-2,2'-bis(di-2-furylphosphino)-1,1'-binaphthalene 4 (TetFuBINAP) is described along with its use in asymmetric inter- and intramolecular Heck reactions. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：263 / 269

页数：7

共 36 条

[1] THE CHEMISTRY OF HETEROARYLPHOSPHORUS COMPOUNDS .15. P-31 NUCLEAR MAGNETIC-RESONANCE STUDIES OF THE DONOR PROPERTIES OF HETEROARYLPHOSPHINES TOWARDS SELENIUM AND PLATINUM(II) [J].

ALLEN, DW ;

TAYLOR, BF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (01) :51-54

[2] A novel resolution procedure for the preparation of P-stereogenic phosphine oxides [J].

Andersen, NG ;

Ramsden, PD ;

Che, DQ ;

Parvez, M ;

Keay, BA .

ORGANIC LETTERS, 1999, 1 (12) :2009-2011

[3] Synthesis, resolution, and applications of 2,2′-bis(diphenylphosphino)-3,3′-binaphtho[2,1-b]furan [J].

Andersen, NG ;

Parvez, M ;

Keay, BA .

ORGANIC LETTERS, 2000, 2 (18) :2817-2820

[4]

[Anonymous], 1999, J CHEM EDUC

[5] Catalytic asymmetric synthesis of quaternary carbon centers.: Exploratory investigations of intramolecular Heck reactions of (E)-α,β-Unsaturated 2-haloanilides and analogues to form enantioenriched spirocyclic products [J].

Ashimori, A ;

Bachand, B ;

Overman, LE ;

Poon, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (26) :6477-6487

[6] CATALYTIC ASYMMETRIC-SYNTHESIS OF QUARTERNARY CARBON CENTERS - PALLADIUM-CATALYZED FORMATION OF EITHER ENANTIOMER OF SPIROOXINDOLES AND RELATED SPIROCYCLICS USING A SINGLE ENANTIOMER OF A CHIRAL DIPHOSPHINE LIGAND [J].

ASHIMORI, A ;

OVERMAN, LE .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (17) :4571-4572

[7] New class of chiral diphosphine ligands for highly efficient transition metal-catalyzed stereoselective reactions: The bis(diphenylphosphino) five-membered biheteroaryls [J].

Benincori, T ;

Brenna, E ;

Sannicolo, F ;

Trimarco, L ;

Antognazza, P ;

Cesarotti, E ;

Demartin, F ;

Pilati, T .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (18) :6244-6251

[8] Synthesis and resolution of 2,2'-bis-diphenylphosphino[3,3']biindolyl; A new atropisomeric ligand for transition metal catalysis [J].

Berens, U ;

Brown, JM ;

Long, J ;

Selke, R .

TETRAHEDRON-ASYMMETRY, 1996, 7 (01) :285-292

[9] New amidophosphine-phosphinites (tLANOPs) as chiral ligands for asymmetric hydrogenation reactions [J].

Broger, EA ;

Burkart, W ;

Hennig, M ;

Scalone, M ;

Schmid, R .

TETRAHEDRON-ASYMMETRY, 1998, 9 (22) :4043-4054

[10] SYNTHESIS OF OPTICALLY-ACTIVE 2,2'-DIHALO-1,1'-BINAPHTHYLS VIA STABLE DIAZONIUM SALTS [J].

BROWN, KJ ;

BERRY, MS ;

MURDOCH, JR .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (22) :4345-4349

← 1 2 3 4 →