Additive-free thiolysis of epoxides in water:: A green and efficient regioselective pathway to β-hydroxy sulfides

被引：22

作者：

Abaee, M. Saeed ^{[1
]}

Mojtahedi, Mohammad M. ^{[1
]}

Abbasi, Hassan ^{[1
]}

Fatemi, Ensieh R. ^{[2
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran

[2] Islamic Azad Univ, Dept Chem, Saveh, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 02期

关键词：

additive-free; aqueous conditions; epoxides; green chemistry; thiolysis;

D O I：

10.1080/00397910701749963

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Room-temperature ring opening of various epoxides with aromatic thiols was carried out in water in the absence of any Lewis acid or additive. High yields of beta-hydroxy sulfides with excellent regioselectivity were obtained under very environmentally friendly conditions.

引用

收藏

页码：282 / 289

页数：8

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