Sustainable Mizoroki-Heck reaction in water:: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid

被引：90

作者：

Hagiwara, H

Sugawara, Y

Hoshi, T

Suzuki, T

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 95021, Japan

[2] Niigata Univ, Fac Engn, Niigata 9502181, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 23期

关键词：

D O I：

10.1039/b502528a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium acetate immobilized on reversed phase amorphous silica gel with the aid of an ionic liquid, [bmim]PF6, was highly efficient in the promotion of the Mizoroki - Heck reaction in pure water without a ligand up to the sixth re-use, in 95% average yield with TON and TOF 1,600,000 and 71,000 (h(-1)), respectively.

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收藏

页码：2942 / 2944

页数：3

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