Immobilization of Pd(OAc)2 in ionic liquid on silica:: Application to sustainable Mizoroki-Heck reaction

被引：186

作者：

Hagiwara, H

Sugawara, Y

Isobe, K

Hoshi, T

Suzuki, T

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[2] Niigata Univ, Fac Engn, Niigata 9502181, Japan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 14期

关键词：

D O I：

10.1021/ol049343i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium acetate was supported on amorphous silica with the aid of an ionic liquid, [bmim]PF6. The immobilized catalyst was highly efficient in promoting the Mizoroki-Heck reaction without a ligand in n-dodecane for at least six reuses, in 89-98% yields. The TON and TOF reached 68 400 and 8000, respectively.

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收藏

页码：2325 / 2328

页数：4

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