The effect of ZnO coating on electrochemical cycling behavior of spinel LiMn2O4 cathode materials at elevated temperature

被引：116

作者：

Sun, YK ^{[1
]}

Hong, KJ

Prakash, J

机构：

[1] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea

[2] IIT, Dept Environm Chem & Engn, Chicago, IL 60616 USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2003年 / 150卷 / 07期

关键词：

D O I：

10.1149/1.1580819

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The structural stability of nanosized ZnO-coated LiMn2O4 was characterized by its cycling behavior at 30 and 55degreesC. The structural degradation and Mn dissolution of the as-prepared and ZnO-coated LiMn2O4 electrodes before and after cycling were studied. The ZnO-coating significantly improved cycling performance at 55degreesC. The reason for the excellent cycling performance of ZnO-coated LiMn2O4 electrode is largely attributed to ZnO's role of HF collection from the electrolyte. (C) 2003 The Electrochemical Society.

引用

页码：A970 / A972

页数：3

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