Surface treatments of Li1+xMn2-xO4 spinels for improved elevated temperature performance

被引：222

作者：

Amatucci, GG

Blyr, A

Sigala, C

Alfonse, P

Tarascon, JM

机构：

[1] BELLCORE, Energy Storage Res Grp, Red Bank, NJ 07701 USA

[2] Univ Toulouse 3, F-32000 Toulouse, France

[3] Univ Picardie, F-80000 Amiens, France

来源：

SOLID STATE IONICS | 1997年 / 104卷 / 1-2期

关键词：

positive electrode; lithium-ion batteries; spinel; surface treatments;

D O I：

10.1016/S0167-2738(97)00407-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

In this paper, we introduce the use of surface treatments to improve the elevated temperature storage characteristics of the Li1+xMn2-xO4 spinel in Li-ion batteries. Two approaches are introduced, the first consists of the application of an inorganic lithium berate glass composition to the surface, the second utilizes an acetylacetone complexing agent. All surface treatments were found to improve the elevated temperature performance of the Li1+xMn2-xO4 spinel to some degree. Results are discussed with respect to the active failure mechanisms.

引用

页码：13 / 25

页数：13

共 18 条

[1]

AMATUCCI GG, IN PRESS J POWER SOU

[2]

BLYR A, IN PRESS J ELECTROCH

[3]

DREHER J, 1993, J POWER SOURCES, V43, P583

[4]

Synthesis and characterization of Li1+xMn2-xO4 for Li-ion battery applications [J].