Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH

被引：28

作者：

Jin, XG

Tang, KL

Jia, SJ

Tang, YQ

机构：

[1] Institute of Physical Chemistry, Peking University

来源：

POLYHEDRON | 1996年 / 15卷 / 15期

关键词：

D O I：

10.1016/0277-5387(95)00544-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The three dimensional polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n) . nCH(3)OH (1) has been synthesized from the reaction of [Cd-4(SPh)(6)(SPh)(4/2)](n) with CS2, DMF and MeOH, and structurally characterized by X-ray diffraction analysis. Its repeat unit is a 17-nuclear cadmium cluster which is linked to four surrounding aggregates through four CH3OSC2- ligands. The method of synthesis is also discussed. Copyright (C) 1996 Elsevier Science Ltd.

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页码：2617 / 2622

页数：6

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