FORMATION AND X-RAY STRUCTURE OF A NOVEL TETRADECANUCLEAR COPPER(I) CLUSTER COMPLEX CU14(MU-2-S)(SPH)12(PPH3)6

被引：27

作者：

TANG, K

XIA, TB

JIN, XL

TANG, YQ

机构：

[1] Institute of Physical Chemistry, Peking University, Beijing

来源：

POLYHEDRON | 1993年 / 12卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)80075-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The neutral tetradecanuclear copper(I) thiolate cluster complex has been formed from the reaction of (Ph3P)2Cu(S2CSPh) with CH2Cl2 and MeOH and structurally characterized by X-ray diffraction analysis. The core of the [Cu14(mu2-S)(SPh)12(PPh3)6] cluster consists of a sulphur ion at the centre of a cube of eight copper(I) atoms form an octahedron and the icosahedron of S12 fits inside the octahedron of Cu.

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页码：2895 / 2898

页数：4

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