Stacked Platinum Complexes of the Magnus' Salt Type Inside a Coordination Cage

被引：113

作者：

Clever, Guido H. ^{[1
,2
]}

Kawamura, Wataru

Tashiro, Shohei ^{[2
]}

Shiro, Motoo

Shionoya, Mitsuhiko ^{[2
]}

机构：

[1] Univ Gottingen, Inst Inorgan Chem, D-37077 Gottingen, Germany

[2] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 11期

关键词：

cage compounds; host-guest systems; metal stacking; platinum; supramolecular chemistry; CRYSTAL-STRUCTURES; GREEN SALT; ENCAPSULATION; CHEMISTRY; PALLADIUM(II); DISCRETE; CAPSULES; GUESTS; CHAINS; HOSTS;

D O I：

10.1002/anie.201108197

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neatly wrapped up: Alternately stacked square-planar platinum(II) complexes inside a dinuclear coordination cage were prepared to give a discrete and soluble Pt 5-array of the Magnus' salt type. Characterization of the complex in solution was complemented by an X-ray crystal structure of {[Pt(pyridine) 4]· [PtCl 4] 2@Cage}; this structure showed the linear, pentanuclear array within the cages and their circular packing into a hollow tubular superstructure. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：2606 / 2609

页数：4

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