Cyano-bridged Re6Q8 (Q = S, Se) cluster-metal framework solids:: A new class of porous materials

被引：193

作者：

Beauvais, LG ^{[1
]}

Shores, MP ^{[1
]}

Long, JR ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 12期

关键词：

D O I：

10.1021/cm980564q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Clusters of the type [Re(6)Q(8)(CN)(6)](4-) (Q = S, Se) are demonstrated to react with a range of divalent transition metal ions in aqueous solution to produce framework materials. The structures of the new phases exhibiting two-dimensional sheets, interpenetrating frameworks with pocket-lined one-dimensional channels, and a three-dimensional network of water-filled cubic cages are described.

引用

页码：3783 / +

页数：5

共 26 条

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