Cyano-bridged Re6Q8 (Q = S, Se) cluster-metal framework solids:: A new class of porous materials

被引：193

作者：

Beauvais, LG ^{[1
]}

Shores, MP ^{[1
]}

Long, JR ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 12期

关键词：

D O I：

10.1021/cm980564q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Clusters of the type [Re(6)Q(8)(CN)(6)](4-) (Q = S, Se) are demonstrated to react with a range of divalent transition metal ions in aqueous solution to produce framework materials. The structures of the new phases exhibiting two-dimensional sheets, interpenetrating frameworks with pocket-lined one-dimensional channels, and a three-dimensional network of water-filled cubic cages are described.

引用

页码：3783 / +

页数：5

共 26 条

[11] HEXACYANOMETALLATE SALTS USED AS ALKENE-OXIDE POLYMERIZATION CATALYSTS AND MOLECULAR-SIEVES
KUYPER, J
BOXHOORN, G
[J]. JOURNAL OF CATALYSIS, 1987, 105 (01) : 163 - 174
[12] NONMOLECULAR METAL CHALCOGENIDE HALIDE SOLIDS AND THEIR MOLECULAR CLUSTER ANALOGS
LEE, SC
HOLM, RH
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (08): : 840 - 856
[13] A solid-state route to molecular clusters: Access to the solution chemistry of [Re(6)Q(8)](2+) (Q=S, Se) core-containing clusters via dimensional reduction
Long, JR
McCarty, LS
Holm, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (19) : 4603 - 4616
[14] SYNTHESIS AND CRYSTAL-STRUCTURE OF A HEXANUCLEAR RHENIUM CLUSTER COMPLEX CS3K[RE-6(MU(3)-S)(6) (MU(3)-TE0.66S0.34)2(CN)(6)] - CATIONIC CONTROL OVER ORIENTATION OF THE CLUSTER ANION
MIRONOV, YV
VIROVETS, AV
FEDOROV, VE
PODBEREZSKAYA, NV
SHISHKIN, OV
STRUCHKOV, YT
[J]. POLYHEDRON, 1995, 14 (20-21) : 3171 - 3173
[15] Cocrystallized mixtures and multiple geometries: Syntheses, structures, and NMR spectroscopy of the Re-6 clusters [NMe(4)](4)[Re-6(Te8-nSen)(CN)(6)] (n=0-8)
Mironov, YV
Cody, JA
AlbrechtSchmitt, TE
Ibers, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (03) : 493 - 498
[16] MOORE JS, 1994, CHEM IND-LONDON, P556
[17] Naumov NG, 1998, ANGEW CHEM INT EDIT, V37, P1943, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1943::AID-ANIE1943>3.0.CO
[18] 2-Q
[19] POSPELOV VA, 1947, ZH FIZ KHIM+, V21, P879
[20] SHORES MP, UNPUB

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