Covalent linking of coordination-organized slipped cofacial porphyrin dimers

被引：43

作者：

Ohashi, A ^{[1
]}

Satake, A ^{[1
]}

Kobuke, Y ^{[1
]}

机构：

[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2004年 / 77卷 / 02期

关键词：

D O I：

10.1246/bcsj.77.365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordination-organized porphyrin chillers of 5,15-bis[2-(allyloxycarbonyl)ethyl]- and bis[3-(allyloxy)propyl]-20-(1- methyl-2-imidazolyl)porphyrinatozine were covalently linked by an intramolecular olefin metathesis reaction in excellent yields (93-98%). It was found that the yields of the intramolecular metathesis reaction depended strongly on the molecular length of the substituent at the 5 and 15 positions. Introducing longer 3-(allyloxycarbonyl)propyl and 4-(allyloxycarbonyl)butyl substituents decreased sharply the yields of the covalent linking reaction to 26% and 16%, respectively. The covalently linked dimers maintained their coordination structures even when dissolved in as polar a solvent as pyridine.

引用

页码：365 / 374

页数：10