Electrospun MEH-PPV/SBA-15 composite nanofibers using a dual syringe method

被引:250
作者
Madhugiri, S [1 ]
Dalton, A [1 ]
Gutierrez, J [1 ]
Ferraris, JP [1 ]
Balkus, KJ [1 ]
机构
[1] Univ Texas, Dept Chem, Richardson, TX 75083 USA
关键词
D O I
10.1021/ja030326i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The process of electrospinning, which produces fibers in the nanometer to micron range under the influence of high voltages, has been widely studied to produce polymer and textile fibers. Mesoporous molecular sieve fibers have been produced in our lab, and this technique was extended to produce an interwoven mesh of polymer-molecular sieve composite fibers. The electroluminescent polymer MEH-PPV and molecular sieve SBA-15 were used to produce the composite fibers. An interesting aspect of these composites is that the fluorescence of MEH-PPV is blue shifted in the composites. The composites have been characterized by microscopy, vibrational spectroscopy, and fluorescence measurements.
引用
收藏
页码:14531 / 14538
页数:8
相关论文
共 39 条
  • [1] Electronic interaction between photoexcited poly(p-phenylene vinylene) and carbon nanotubes
    Ago, H
    Shaffer, MSP
    Ginger, DS
    Windle, AH
    Friend, RH
    [J]. PHYSICAL REVIEW B, 2000, 61 (03): : 2286 - 2290
  • [2] Ultrafast and long-lived photoinduced charge separation in MEH-PPV/nanoporous semiconductor thin film composites
    Anderson, NA
    Hao, EC
    Ai, X
    Hastings, G
    Lian, TQ
    [J]. CHEMICAL PHYSICS LETTERS, 2001, 347 (4-6) : 304 - 310
  • [3] Charge transfer in photovoltaics consisting of interpenetrating networks of conjugated polymer and TiO2 nanoparticles
    Arango, AC
    Carter, SA
    Brock, PJ
    [J]. APPLIED PHYSICS LETTERS, 1999, 74 (12) : 1698 - 1700
  • [4] BALKUS KJ, 2001, MATER RES SOC S P, V628, P1
  • [5] Bognitzki M, 2001, ADV MATER, V13, P70, DOI 10.1002/1521-4095(200101)13:1<70::AID-ADMA70>3.0.CO
  • [6] 2-H
  • [7] INFRARED CHARACTERIZATION OF ORIENTED POLY(PHENYLENE VINYLENE)
    BRADLEY, DDC
    FRIEND, RH
    LINDENBERGER, H
    ROTH, S
    [J]. POLYMER, 1986, 27 (11) : 1709 - 1713
  • [8] Photoinduced electron transfer from conjugated polymers onto TiO2
    Christiaans, MPT
    Wienk, MM
    van Hal, PA
    Kroon, JM
    Janssen, RAJ
    [J]. SYNTHETIC METALS, 1999, 101 (1-3) : 265 - 266
  • [9] Controlling the optical properties of a conjugated co-polymer through variation of backbone isomerism and the introduction of carbon nanotubes
    Dalton, AB
    Coleman, JN
    Panhuis, MIH
    McCarthy, B
    Drury, A
    Blau, WJ
    Paci, B
    Nunzi, JM
    Byrne, HJ
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 144 (01) : 31 - 41
  • [10] DIETZEL JM, 2001, POLYMER, V42, P261