Electrospun MEH-PPV/SBA-15 composite nanofibers using a dual syringe method

被引:250
作者
Madhugiri, S [1 ]
Dalton, A [1 ]
Gutierrez, J [1 ]
Ferraris, JP [1 ]
Balkus, KJ [1 ]
机构
[1] Univ Texas, Dept Chem, Richardson, TX 75083 USA
关键词
D O I
10.1021/ja030326i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The process of electrospinning, which produces fibers in the nanometer to micron range under the influence of high voltages, has been widely studied to produce polymer and textile fibers. Mesoporous molecular sieve fibers have been produced in our lab, and this technique was extended to produce an interwoven mesh of polymer-molecular sieve composite fibers. The electroluminescent polymer MEH-PPV and molecular sieve SBA-15 were used to produce the composite fibers. An interesting aspect of these composites is that the fluorescence of MEH-PPV is blue shifted in the composites. The composites have been characterized by microscopy, vibrational spectroscopy, and fluorescence measurements.
引用
收藏
页码:14531 / 14538
页数:8
相关论文
共 39 条
  • [21] Marlow F, 1999, ADV MATER, V11, P632, DOI 10.1002/(SICI)1521-4095(199906)11:8<632::AID-ADMA632>3.0.CO
  • [22] 2-Q
  • [23] Ultrafast photoinduced charge generation in conjugated polymers
    Moses, D
    Dogariu, A
    Heeger, AJ
    [J]. CHEMICAL PHYSICS LETTERS, 2000, 316 (5-6) : 356 - 360
  • [24] MEH-PPV: Improved synthetic procedure and molecular weight control
    Neef, CJ
    Ferraris, JP
    [J]. MACROMOLECULES, 2000, 33 (07) : 2311 - 2314
  • [25] Nguyen TQ, 2001, ADV MATER, V13, P609, DOI 10.1002/1521-4095(200104)13:8<609::AID-ADMA609>3.0.CO
  • [26] 2-#
  • [27] Electrostatic fabrication of ultrafine conducting fibers: polyaniline/polyethylene oxide blends
    Norris, ID
    Shaker, MM
    Ko, FK
    MacDiarmid, AG
    [J]. SYNTHETIC METALS, 2000, 114 (02) : 109 - 114
  • [28] Conjugation length control in soluble poly[2-methoxy-5-((2′-ethylhexyl)oxy)-1,4-phenylenevinylene] (MEHPPV):: Synthesis, optical properties, and energy transfer
    Padmanaban, G
    Ramakrishnan, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (10) : 2244 - 2251
  • [29] Nanometre diameter fibres of polymer, produced by electrospinning
    Reneker, DH
    Chun, I
    [J]. NANOTECHNOLOGY, 1996, 7 (03) : 216 - 223
  • [30] Interchain and intrachain exciton transport in conjugated polymers: ultrafast studies of energy migration in aligned MEH-PPV/mesoporous silica composites
    Schwartz, BJ
    Nguyen, TQ
    Wu, JJ
    Tolbert, SH
    [J]. SYNTHETIC METALS, 2001, 116 (1-3) : 35 - 40