Ir(III)-induced C-bound to N-bound tautomerization of a N-heterocyclic carbene

被引：64

作者：

Wang, Xinjiao ^{[1
]}

Chen, Hongyu ^{[1
]}

Li, Xingwei ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Math & Phys Sci, Singapore 637616, Singapore

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 18期

关键词：

D O I：

10.1021/om700498w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An iridium N-heterocyclic carbene (NHC) complex with a rare hydrogen wing tip was obtained via C-N bond cleavage. The C-bound to N-bound tautomerization of this carbene cannot be achieved in this neutral 18-electron Ir(III) complex. Chloride abstraction in MeCN afforded an NHC-acetimidamide complex, where the N-bound to C-bound tautomerization of this carbene was observed in CDCl3 at 110 degrees C. Crystal structures of iridium complexes with these rare ligands were reported.

引用

页码：4684 / 4687

页数：4

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