Photon-stimulated ion desorption for PMMA thin film in the oxygen K-edge region studied by Auger electron-photoion coincidence spectroscopy

被引:27
作者
Ikenaga, E
Kudara, K
Kusaba, K
Isari, K
Sardar, SA
Wada, S
Mase, K
Sekitani, T [1 ]
Tanaka, K
机构
[1] Hiroshima Univ, Dept Phys Sci, Higashihiroshima 7398526, Japan
[2] Hiroshima Univ, Ctr Synchrotron Radiat, Higashihiroshima 7398526, Japan
[3] Inst Mat Struct Sci, Tsukuba, Ibaraki 3050801, Japan
基金
日本学术振兴会;
关键词
photon-stimulated desorption (PSD); poly-methylmethacrylate (PMMA); auger electron spectroscopy (AES); auger electron-photoion coincidence (AEPICO);
D O I
10.1016/S0368-2048(00)00325-X
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Auger electron-photoion coincidence (AEPICO) measurements have been performed for poly-methylmethacrylate (PMMA) thin films induced by oxygen core excitation. The dominant productions of CHn+ (n=1-3) ions were observed at resonant excitation to o-CH3 anti-bonding state, and OCH+ ion was observed at resonant excitation to C-OCH3 anti-bonding state. Their AEPICO yields were strongly dependent on Anger electron kinetic energy and shows enhancement around 505 eV Anger electron energy for each ion. This seems to be related to the spectator resonant Anger-stimulated ion desorption. The correlation between ion desorption and Anger final state for PMMA. thin films in the oxygen K-edge region is discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:585 / 590
页数:6
相关论文
共 21 条
[1]  
DEBRITO AN, 1991, SURF INTERFACE ANAL, V17, P94
[2]   A THEORETICAL-STUDY OF X-RAY PHOTOELECTRON-SPECTRA OF MODEL MOLECULES FOR POLYMETHYLMETHACRYLATE [J].
DEBRITO, AN ;
CORREIA, N ;
SVENSSON, S ;
AGREN, H .
JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (04) :2965-2974
[3]   ADSORBATE CORE IONIZATION AS PRIMARY PROCESS IN ELECTRON-STIMULATED AND PHOTON-STIMULATED DESORPTION FROM METAL-SURFACES [J].
FRANCHY, R ;
MENZEL, D .
PHYSICAL REVIEW LETTERS, 1979, 43 (12) :865-867
[4]  
IKENAGA E, IN PRESS J CHEM PHYS
[5]   ION DESORPTION BY CORE-HOLE AUGER DECAY [J].
KNOTEK, ML ;
FEIBELMAN, PJ .
PHYSICAL REVIEW LETTERS, 1978, 40 (14) :964-967
[6]   Auger electron photoion coincidence technique combined with synchrotron radiation for the study of the ion desorption mechanism in the region of resonant transitions of condensed H2O [J].
Mase, K ;
Nagasono, M ;
Tanaka, S ;
Urisu, T ;
Ikenaga, E ;
Sekitani, T ;
Tanaka, K .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (16) :6550-6553
[7]   Ion desorption induced by core-electron transitions studied with electron-ion coincidence spectroscopy [J].
Mase, K ;
Tanaka, S ;
Nagaoka, S ;
Urisu, T .
SURFACE SCIENCE, 2000, 451 (1-3) :143-152
[8]   Development of electron-ion coincidence spectroscopy for the study of surface dynamics combined with synchrotron radiation [J].
Mase, K ;
Nagasono, M ;
Tanaka, S ;
Kamada, M ;
Urisu, T ;
Murata, Y .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (04) :1703-1707
[9]   State-selected ion desorption from condensed H2O at 80 K studied by Auger electron-photoion coincidence spectroscopy [J].
Nagasono, M ;
Mase, K ;
Tanaka, S ;
Urisu, T .
CHEMICAL PHYSICS LETTERS, 1998, 298 (1-3) :141-145
[10]   Auger-final-state selected ion desorption study of condensed NH3 and ND3 by using Auger electron-photoion coincidence spectroscopy [J].
Nagasono, M ;
Mase, K ;
Tanaka, S ;
Urisu, T .
SURFACE SCIENCE, 1997, 377 (1-3) :380-383