Asymmetric allylation of aromatic aldehydes catalyzed by chiral phosphoramides prepared from (S)-proline

被引：101

作者：

Iseki, K

Kuroki, Y

Takahashi, M

Kishimoto, S

Kobayashi, Y

机构：

[1] MEC Laboratory, Daikin Industries, Ltd., Tsukuba, Ibaraki 305, Miyukigaoka

来源：

TETRAHEDRON | 1997年 / 53卷 / 10期

关键词：

D O I：

10.1016/S0040-4020(97)00084-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral phosphoramides prepared from (S)-proline were used to catalyze the allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes in good enantioselective yields. Phosphoramides 4d and 4m gave chiral homoallylic alcohols and their enantiomers, respectively, with similar levels of enantioselectivity. (C) 1997 Elsevier Science Ltd.

引用

页码：3513 / 3526

页数：14

共 41 条

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