Metal oxide nano-particles for improved electrochromic and lithium-ion battery technologies

被引：70

作者：

Dillon, A. C. ^{[1
]}

Mahan, A. H. ^{[1
]}

Deshpande, R. ^{[1
]}

Parilla, Ra. ^{[1
]}

Jones, K. M. ^{[1
]}

Lee, S-H. ^{[1
]}

机构：

[1] Natl Renewable Energy Lab, Golden, CO 80401 USA

来源：

THIN SOLID FILMS | 2008年 / 516卷 / 05期

关键词：

hot-wire chemical vapor deposition; metal oxide nano-particles; electrochromic; lithium-ion battery;

D O I：

10.1016/j.tsf.2007.06.177

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Hot-wire chemical vapor deposition (HWCVD) has been employed as an economically scalable method for the deposition of crystalline tungsten oxide nano-rods and nano-particles. Under optimal synthesis conditions, only crystalline WO3 nano-structures with a smallest dimension of similar to 10-50 nm are observed with extensive transmission electron microscopy (TEM) analyses. The incorporation of these particles into porous films led to profound advancement in state-of-the-art electrochromic (EC) technologies. HWCVD has also been employed to produce crystalline molybdenum oxide nano-rods, particles and tubes at high density. TEM analyses show that the smallest dimension of these nano-structures is similar to 5-30 nm. XRD and Raman analyses reveal that the materials are highly crystalline and consist of Mo, MoO2 and MoO3 phases. It is also possible to fabricate large-area porous films containing these MoOx, nano-structures. Furthermore, these films have been tested as the negative electrode in lithium-ion batteries, and a surprisingly high, reversible capacity has been observed. (c) 2007 Elsevier B.V. All tights reserved.

引用

页码：794 / 797

页数：4

共 8 条

[1] Continuous hot wire chemical vapor deposition of high-density carbon multiwall nanotubes [J].