Surface-modified meso-carbon microbeads anode for dry polymer lithium-ion batteries

被引:44
作者
Imanishi, N. [1 ]
Ono, Y. [1 ]
Hanai, K. [1 ]
Uchiyama, R. [1 ]
Liu, Y. [1 ]
Hirano, A. [1 ]
Takeda, Y. [1 ]
Yamamoto, O. [1 ]
机构
[1] Mie Univ, Fac Engn, Dept Chem, Tsu, Mie 5148507, Japan
关键词
carbon anode; MCMB; lithium-ion battery; dry polymer battery;
D O I
10.1016/j.jpowsour.2007.09.035
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A high-anode performance for dry polymer lithium-ion batteries was obtained in the surface-modified meso-carbon microbeads (MCMB). MCMB and polyvinylchloride (PVC) mixture was heated at 700 degrees C for 6 h under inert atmosphere. By this treatment, the surface of MCMB is covered with low-crystallin e carbon material derived from PVC pyrolysis. The surface-modified MCMB electrode applied to dry polymer electrolytes shows a reversible capacity of 300 mAh g(-1), which is comparable to those obtained in the liquid electrolyte systems. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:744 / 750
页数:7
相关论文
共 21 条
[11]  
KAPFER B, 1990, P S PRIM SEC LITH BA, P227
[12]   Characteristics of carbon-coated graphite prepared from mixture of graphite and polyvinylchloride as anode materials for lithium ion batteries [J].
Lee, HY ;
Baek, JK ;
Jang, SW ;
Lee, SM ;
Hong, ST ;
Lee, KY ;
Kim, MH .
JOURNAL OF POWER SOURCES, 2001, 101 (02) :206-212
[13]   Four volts class solid lithium polymer batteries with a composite polymer electrolyte [J].
Li, Q ;
Imanishi, N ;
Hirano, A ;
Takeda, Y ;
Yamamoto, O .
JOURNAL OF POWER SOURCES, 2002, 110 (01) :38-45
[14]   Novel composite anodes consisting of lithium transition-metal nitrides and transition metal oxides for rechargeable Li-ion batteries [J].
Liu, Y ;
Takeda, Y ;
Matsumura, T ;
Yang, J ;
Imanishi, N ;
Hirano, A ;
Yamamoto, O .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (02) :A437-A444
[15]   Silicon/carbon composites as anode materials for Li-ion batteries [J].
Liu, Y ;
Hanai, K ;
Yang, J ;
Imanishi, N ;
Hirano, A ;
Takeda, Y .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (10) :A369-A372
[16]   THE ELECTROCHEMICAL-BEHAVIOR OF ALKALI AND ALKALINE-EARTH METALS IN NON-AQUEOUS BATTERY SYSTEMS - THE SOLID ELECTROLYTE INTERPHASE MODEL [J].
PELED, E .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (12) :2047-2051
[17]   Dendrite short-circuit and fuse effect on Li/polymer/Li cells [J].
Rosso, Michel ;
Brissot, Claire ;
Teyssot, Anna ;
Dolle, Michael ;
Sannier, Lucas ;
Tarascon, Jean-Marie ;
Bouchetc, Renaud ;
Lascaud, Stephane .
ELECTROCHIMICA ACTA, 2006, 51 (25) :5334-5340
[18]   Effect of graphite surface structure on initial irreversible reaction in graphite anodes [J].
Suzuki, K ;
Hamada, T ;
Sugiura, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (03) :890-897
[19]   Surface modification of natural graphite particles for lithium ion batteries [J].
Tsumura, T ;
Katanosaka, A ;
Souma, I ;
Ono, T ;
Aihara, Y ;
Kuratomi, J ;
Inagaki, M .
SOLID STATE IONICS, 2000, 135 (1-4) :209-212
[20]   Lithium insertion into Sn- and SnSbx-based composite electrodes in solid polymer electrolytes [J].
Yang, J ;
Takeda, Y ;
Li, Q ;
Imanishi, N ;
Yamamoto, O .
JOURNAL OF POWER SOURCES, 2000, 90 (01) :64-69