Synthesis of maleimide-terminated n-butyl acrylate oligomers by atom transfer radical polymerization:: Study of their copolymerization with vinyl ethers

被引：22

作者：

Boyer, C ^{[1
]}

Otazaghine, B ^{[1
]}

Boutevin, B ^{[1
]}

Joly-Duhamel, C ^{[1
]}

Robin, JJ ^{[1
]}

机构：

[1] CNRS, Ecole Natl Super Chim Montpellier, Lab Chim Macromol, UMR 5076, F-34296 Montpellier, France

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2005年 / 43卷 / 18期

关键词：

maleimide; photochemistry; atom transfer radical polymerization;

D O I：

10.1002/pola.20878

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of maleimide (aliphatic or aromatic) terminated poly(n-butyl acrylate) oligomers based on the atom transfer radical polymerization (ATRP) method was analyzed. The oligomers with an aromatic maleimide-terminated function were obtained by using a new initiator with an aliphatic amine function for the ATRP step. The obtained maleimide-terminated oligomers were copolymerized with divinyl ether under UV irradiation with or without photoinitiator. The Fourier transform infrared spectroscopy (FTIR) study of these copolymerizations showed a really higher reactivity of the aliphatic maleimide.

引用

页码：4303 / 4322

页数：20

共 45 条

[1]

BAS GG, 2004, J POLYM SCI A, V42, P894

[2]

BIANCHI C, 2001, THESIS U HAUTE ALSAC

[3] Photopolymerization of 1,6-hexanedioldiacrylate initiated by three-component systems based on N-arylphthalimides [J].

Cavitt, TB ;

Phillips, B ;

Hoyle, CE ;

Pan, B ;

Hait, SB ;

Viswanathan, K ;

Jönsson, S .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (16) :4009-4015

[4]

CLARK SC, 1998, RADT 98 P CHIC

[5]

Coca S, 1998, J POLYM SCI POL CHEM, V36, P1417, DOI 10.1002/(SICI)1099-0518(19980715)36:9<1417::AID-POLA9>3.0.CO

[6]

2-P

[7] NITROGEN-CONTAINING MONOMERS .1. COPOLYMERIZATION REACTIONS OF N-ALKYL MALEAMIC ACIDS AND N-ALKYL MALEIMIDES [J].

COLEMAN, LE ;

CONRADY, JA .

JOURNAL OF POLYMER SCIENCE, 1959, 38 (133) :241-245

[8]

Cuppon R. C. P., 1965, POLYMER, V6, P419

[9]

Decker C, 2000, MACROMOL CHEM PHYS, V201, P1493, DOI 10.1002/1521-3935(20000801)201:13<1493::AID-MACP1493>3.0.CO

[10]

2-N

← 1 2 3 4 5 →