Synthesis of maleimide-terminated n-butyl acrylate oligomers by atom transfer radical polymerization:: Study of their copolymerization with vinyl ethers

被引：22

作者：

Boyer, C ^{[1
]}

Otazaghine, B ^{[1
]}

Boutevin, B ^{[1
]}

Joly-Duhamel, C ^{[1
]}

Robin, JJ ^{[1
]}

机构：

[1] CNRS, Ecole Natl Super Chim Montpellier, Lab Chim Macromol, UMR 5076, F-34296 Montpellier, France

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2005年 / 43卷 / 18期

关键词：

maleimide; photochemistry; atom transfer radical polymerization;

D O I：

10.1002/pola.20878

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of maleimide (aliphatic or aromatic) terminated poly(n-butyl acrylate) oligomers based on the atom transfer radical polymerization (ATRP) method was analyzed. The oligomers with an aromatic maleimide-terminated function were obtained by using a new initiator with an aliphatic amine function for the ATRP step. The obtained maleimide-terminated oligomers were copolymerized with divinyl ether under UV irradiation with or without photoinitiator. The Fourier transform infrared spectroscopy (FTIR) study of these copolymerizations showed a really higher reactivity of the aliphatic maleimide.

引用

页码：4303 / 4322

页数：20

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