Photocatalytic water splitting over Pt-TiO2 in the presence of sacrificial reagents

被引：314

作者：

Galinska, A ^{[1
]}

Walendziewski, J ^{[1
]}

机构：

[1] Wroclaw Univ Technol, Inst Chem & Technol Petr & Coal, PL-50310 Wroclaw, Poland

来源：

ENERGY & FUELS | 2005年 / 19卷 / 03期

关键词：

D O I：

10.1021/ef0400619

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Hydrogen production by water splitting over a Pt-TiO2 catalyst has been studied. The main goal of the studies was to examine the influence of sacrificial reagents on the photocatalytic efficiency in water splitting reactions under ultraviolet (UV) irradiation. Various sacrificial reagents, such as methanol, Na2S, and ethylene diamine tetraacetic acid (EDTA), as well as land IO3- ions, were used to obtain an effective water splitting to H and O atoms. It was revealed that, in the case of using methanol as the sacrificial reagent, hydrogen evolution is also a result of methanol conversion. Photocatalytic water splitting was obtained when EDTA and Na2S were used as the sacrificial reagents.

引用

页码：1143 / 1147

页数：5

共 28 条

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