Efficient osmiun/rhenium-catalyzed dihydroxylation of olefins with hydrogen peroxide under acidic conditions

被引：18

作者：

Éll, AH ^{[1
]}

Closson, A ^{[1
]}

Adolfsson, H ^{[1
]}

Bäckvall, JE ^{[1
]}

机构：

[1] Stockholm Univ, Dept Organ Chem, S-10691 Stockholm, Sweden

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 08期

关键词：

alkenes; dihydroxylation; homogeneous catalysis; osmium; oxidation;

D O I：

10.1002/adsc.200303043

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Simple addition of citric acid confers great stability to the catalytically active osmium and rhenium species involved in a triple catalytic system utilizing aqueous hydrogen peroxide as the terminal oxidant. The resulting system is capable of dihydroxylating traditionally resistant olefins in high yields.

引用

页码：1012 / 1016

页数：5

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