An unprecedented oxidative migration of a methyl group from 2-(2′,6′-dimethylphenylazo)-4-methylphenol mediated by ruthenium and osmium

被引：55

作者：

Acharyya, R

Peng, SM

Lee, GH

Bhattacharya, S ^{[1
]}

机构：

[1] Jadavpur Univ, Inorgan Chem Sect, Dept Chem, Kolkata 700032, W Bengal, India

[2] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 23期

关键词：

D O I：

10.1021/ic034968i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unprecedented chemical transformation of 2-(2',6'-dimethylphenylazo)-4-methyl phenol has been observed upon its reaction with [M(PPh3)(3)X-2] (M = Ru, Os; X = Cl, Br) whereby one methyl group from the phenyl ring of the arylazo fragment migrates to the metal center via oxidation to CO.

引用

页码：7378 / 7380

页数：3

共 24 条

[21] Chemistry of 2-(arylazo)phenolate complexes of ruthenium. Synthesis, structure and reactivities [J].