A chiral amidophosphine bearing a P-N bond and its pi-allyl palladium(II) chemistry

被引：16

作者：

Hosokawa, T

Wakabayashi, Y

Hosokawa, K

Tsuji, T

Murahashi, SI

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 07期

关键词：

D O I：

10.1039/cc9960000859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Camphor lactam phosphines 1 and 2, prepared from D-camphoric acid and D-camphor, respectively, act as bidentate P,O-ligands of palladium(II) where 1 is less hemilabile than 2, and in the dynamic behaviour of (pi-allyl)palladium(II) complex 8 bearing 1, the bidentate coordination of this ligand is retained.

引用

收藏

页码：859 / 860

页数：2

相关论文

共 13 条

[1] COORDINATION CHEMISTRY AND CATALYSIS WITH HEMILABILE OXYGEN PHOSPHORUS LIGANDS [J].

BADER, A ;

LINDNER, E .

COORDINATION CHEMISTRY REVIEWS, 1991, 108 (01) :27-110

[2] AN UNUSUAL, SELECTIVE ETA(3)-ETA(1) ALLYL ISOMERIZATION IN A CHIRAL ALLYLIC ALKYLATION CATALYST [J].

BREUTEL, C ;

PREGOSIN, PS ;

SALZMANN, R ;

TOGNI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) :4067-4068

[3] HEMILABILE P,O-LIGANDS IN PALLADIUM-CATALYZED C-C LINKAGES - CODIMERIZATION OF ETHYLENE AND STYRENE AND COOLIGOMERIZATION OF ETHYLENE AND CARBON-MONOXIDE [J].

BRITOVSEK, GJP ;

KEIM, W ;

MECKING, S ;

SAINZ, D ;

WAGNER, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (21) :1632-1634

[4] CHELATING AND HEMILABILE PROPERTIES OF BETA-KETO PHOSPHINES AND GAMMA-KETO PHOSPHINES - (ETA(6)-ARENE)RUTHENIUM(II) DERIVATIVES FROM GAMMA-KETO PHOSPHINES AND SYNTHESIS AND REACTIVITY OF BIS(ETA(2)-KETO PHOSPHINE-P,O)RUTHENIUM(II) COMPLEXES [J].

DEMERSEMAN, B ;

LELAGADEC, R ;

GUILBERT, B ;

RENOUARD, C ;

CROCHET, P ;

DIXNEUF, PH .

ORGANOMETALLICS, 1994, 13 (06) :2269-2283

[5] MECHANISM OF APPARENT PI-ALLYL ROTATION IN (PI-ALLYL)PALLADIUM COMPLEXES WITH BIDENTATE NITROGEN LIGANDS [J].

GOGOLL, A ;

ORNEBRO, J ;

GRENNBERG, H ;

BACKVALL, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3631-3632

[6] PALLADIUM PI-ALLYL CHEMISTRY OF NEW P,S BIDENTATE LIGANDS - SELECTIVE BUT VARIABLE DYNAMICS IN THE ISOMERIZATION OF THE ETA(3)-C3H5 AND ETA(3)-PHCHCHCHPH PI-ALLYL LIGANDS [J].

HERRMANN, J ;

PREGOSIN, PS ;

SALZMANN, R ;

ALBINATI, A .

ORGANOMETALLICS, 1995, 14 (07) :3311-3318

[7] ENANTIOSELECTIVE CONJUGATE ADDITION OF ORGANOCUPRATE USING A CHIRAL AMIDOPHOSPHINE LIGAND [J].

KANAI, M ;

KOGA, K ;

TOMIOKA, K .

TETRAHEDRON LETTERS, 1992, 33 (47) :7193-7196

[8] ASYMMETRIC CONJUGATE ADDITION OF ORGANOCOPPER AMIDOPHOSPHINE REAGENTS TO CYCLOALKENONES [J].

KANAI, M ;

TOMIOKA, K .

TETRAHEDRON LETTERS, 1994, 35 (06) :895-898

[9] THE SYNTHESIS AND CRYSTAL-STRUCTURE OF A REMARKABLE BINUCLEAR, DOUBLE PD-CL-H-O-PD BRIDGED PALLADIUM ALCOHOL COMPLEX - CATALYTIC OXIDATIONS WITH MOLECULAR-OXYGEN MEDIATED BY [([ME2C(OH)CH2CONME2]PD(CL)NO2)2] [J].

KIERS, NH ;

FERINGA, BL ;

KOOIJMAN, H ;

SPEK, AL ;

VANLEEUWEN, PWNM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1169-1170

[10] P-31, C-13, AND H-1-NMR STUDIES ON CHIRAL ALLYL FERROCENYLDIPHOSPHINE COMPLEXES OF PALLADIUM(II) [J].

PREGOSIN, PS ;

SALZMANN, R ;

TOGNI, A .

ORGANOMETALLICS, 1995, 14 (02) :842-847